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Keegan Bradley made five birdies and an eagle for a seven-under 65 and a two-shot lead.
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Rory McIlroy is five shots back after a two-under 70.
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K.J. Choi made seven birdies and three bogeys for a four-under 68.
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Lee Westwood made an eagle on the par-5 14th on his way to a three-under 69.
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Adam Scott made three birdies on the back nine to shoot a 69.
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Nick Watney made five birdies and four bogeys for a 71.